Trinchillo, Marina (2016) NOVEL AU(I)-BASED MOLECULAR CATALYSTS: FROM KNOW HOW TO KNOW WHY. [Tesi di dottorato]
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| Item Type: | Tesi di dottorato |
|---|---|
| Resource language: | English |
| Title: | NOVEL AU(I)-BASED MOLECULAR CATALYSTS: FROM KNOW HOW TO KNOW WHY |
| Creators: | Creators Email Trinchillo, Marina MARINA.TRINCHILLO@UNINA.IT |
| Date: | 31 March 2016 |
| Number of Pages: | 254 |
| Institution: | Università degli Studi di Napoli Federico II |
| Department: | Scienze Chimiche |
| Scuola di dottorato: | Scienze chimiche |
| Dottorato: | Scienze chimiche |
| Ciclo di dottorato: | 28 |
| Coordinatore del Corso di dottorato: | nome email Paduano, Luigi LPADUANO@UNINA.IT |
| Tutor: | nome email Busico, Vincenzo UNSPECIFIED D'Amora, Angela UNSPECIFIED |
| Date: | 31 March 2016 |
| Number of Pages: | 254 |
| Keywords: | GOLD CATALYSIS - HOMOGENEOUS CATALYSIS - ALKOXYLATION - ANION EFFECT - NHC COMPOUNDS - FUNCTIONALIZED NHC LIGANDS - ANTIPROLIFERATIVE ACTIVITY |
| Settori scientifico-disciplinari del MIUR: | Area 03 - Scienze chimiche > CHIM/03 - Chimica generale e inorganica |
| Date Deposited: | 11 Apr 2016 17:03 |
| Last Modified: | 20 May 2017 01:00 |
| URI: | http://www.fedoa.unina.it/id/eprint/11000 |
Collection description
In recent years, linear gold(I) complexes have been vastly employed in both homogeneous catalysis and medicinal applications, as anticancer agents. In this thesis novel Au(I)-complexes have been synthesized and their catalytic behavior has been deeply studied in the hydroalkoxylation reaction of alkynes, with particular focus on the role of the anion in different steps of the catalytic cycle, obtaining very interesting results. Furthermore, gold(I) compounds were screened for their antiproliferative effects on different cell lines, and in some cases very promising cytotoxic properties were found.
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