De Lisio, Corrado and D'Alessio, Antonio (2006) Characterization of ultrafast fluorescence from nanometric carbon particles. [Pubblicazione in rivista scientifica]

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Original publication URL: stacks.iop.org/JOptA/8/S578
Item Type: Pubblicazione in rivista scientifica
Resource language: English
Title: Characterization of ultrafast fluorescence from nanometric carbon particles
Creators:
Creators
Email
De Lisio, Corrado
UNSPECIFIED
D'Alessio, Antonio
UNSPECIFIED
Autore/i: A. Bruno, C. de Lisio, P. Minutolo, A. D'Alessio
Date: 2006
Number of Pages: 7
Department: Scienze fisiche
Identification Number: 10.1088/1464-4258/8/7/S44
Original publication URL: stacks.iop.org/JOptA/8/S578
Journal or Publication Title: JOURNAL OF OPTICS. A, PURE AND APPLIED OPTICS
Publisher: IOP Publishing Limited:Dirac House, Temple Back, Bristol BS1 6BE United Kingdom:011 44 117 9297481, EMAIL: custserv@iop.org, INTERNET: http://www.iop.org, Fax: 011 44 117 9294318
Date: 2006
Volume: 8
Page Range: S578-S584
Number of Pages: 7
Keywords: Nanometric particles, Fluorescence anisotropy, Carbon particles
Identification Number: 10.1088/1464-4258/8/7/S44
Date Deposited: 20 Oct 2010 08:01
Last Modified: 30 Apr 2014 19:42
URI: http://www.fedoa.unina.it/id/eprint/6546

Collection description

We present two distinct implementations of the time resolved fluorescence polarization anisotropy (TRFPA) technique for the analysis of carbon nanoparticles collected from laminar laboratory flames and from the exhaust of a gasoline vehicle engine. By exploiting the high time-resolution and the spectral resolution of our TRFPA setups, we could identify two groups of particles, with diameter of 1.4 and 2.2 nm, respectively, within the laminar flame sample. On the other hand, the high time-resolution TRFPA analysis of the gasoline sample led to the identification of two distinct decay channels. The slower one was consistent with a single kind of small particle with diameter of 1.3 nm. Moreover, an analysis of the fast decay versus the temperature allowed us to rule out that it was due to the presence of lighter particles within the sample. Most likely, it is related to the relaxation of internal degrees of freedom.

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