Capelli, Luigia (2010) Synthesis and reactivity of new phenolic and/or heteroaromatic systems of potential practical interest. [Tesi di dottorato] (Inedito)
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| Tipologia del documento: | Tesi di dottorato |
|---|---|
| Lingua: | English |
| Titolo: | Synthesis and reactivity of new phenolic and/or heteroaromatic systems of potential practical interest |
| Autori: | Autore Email Capelli, Luigia luigia.capelli@unina.it |
| Data: | 30 Novembre 2010 |
| Numero di pagine: | 168 |
| Istituzione: | Università degli Studi di Napoli Federico II |
| Dipartimento: | Chimica organica e biochimica |
| Scuola di dottorato: | Scienze chimiche |
| Dottorato: | Scienze chimiche |
| Ciclo di dottorato: | 23 |
| Coordinatore del Corso di dottorato: | nome email Previtera, Lucio previter@unina.it |
| Tutor: | nome email D'Ischia, Marco dischia@unina.it Manini, Paola pmanini@unina.it |
| Data: | 30 Novembre 2010 |
| Numero di pagine: | 168 |
| Parole chiave: | 5,6-dihydroxyindole;synthesis |
| Settori scientifico-disciplinari del MIUR: | Area 03 - Scienze chimiche > CHIM/06 - Chimica organica |
| Depositato il: | 02 Dic 2010 08:15 |
| Ultima modifica: | 30 Apr 2014 19:45 |
| URI: | http://www.fedoa.unina.it/id/eprint/8243 |
| DOI: | 10.6092/UNINA/FEDOA/8243 |
Abstract
My research project has been directed to the synthesis and characterization of a number of selected phenolic and/or heteroaromatic systems and their derivatives for preparation of new molecular scaffolds of potential practical interest. Most of the activity has therefore been directed to the preparation of new derivatives from 5,6-dihydroxyindole (DHI), the fundamental monomer precursors of eumelanins, and 17β-estradiol, an important human and mammal steroidal hormone, selected as biologically relevant building blocks. In particular Chapter 1 of this thesis is devoted to the synthesis of 5,6-dihydroxyindole oligomers, Chapter 2 to the synthesis and reactivity of new alkynyl-derivatives of DHI, Chapter 3 to the synthesis of new alkynyl-derivatives of 17β-estradiol. The last chapter of this thesis, Chapter 4, concerns the results of experiments started during my Master thesis and regarding the synthesis and reactivity of 9- and 10-nitrolinoleic acids, two important nitrated derivatives of linoleic acid, under physiologically relevant conditions.
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