Bernardo, Raffaele (2013) Fundamental investigation and screening of iminato based titanium catalysts. [Tesi di dottorato]

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Item Type: Tesi di dottorato
Lingua: English
Title: Fundamental investigation and screening of iminato based titanium catalysts
Creators:
CreatorsEmail
Bernardo, Raffaeleraffaele.bernardo@unina.it
Date: 2 April 2013
Number of Pages: 133
Institution: Università degli Studi di Napoli Federico II
Department: Scienze Chimiche
Scuola di dottorato: Scienze chimiche
Dottorato: Scienze chimiche
Ciclo di dottorato: 25
Coordinatore del Corso di dottorato:
nomeemail
Previtera, Luciopreviter@unina.it
Tutor:
nomeemail
Busico, Vincenzobusico@unina.it
Cipullo, Robertarcipullo@unina.it
Date: 2 April 2013
Number of Pages: 133
Uncontrolled Keywords: Catalysis
Settori scientifico-disciplinari del MIUR: Area 03 - Scienze chimiche > CHIM/03 - Chimica generale e inorganica
Date Deposited: 05 Apr 2013 05:57
Last Modified: 18 Apr 2016 01:00
URI: http://www.fedoa.unina.it/id/eprint/9195

Abstract

The thesis is oriented to the fundamental study and screening of a class of iminato based Ti catalysts, aimed to the copolymerization processes. The high throughput experimentation (HTE) tools and methods, could be, in principle, of extreme help in speeding-up the development of new systems, featuring higher TOF and satisfying certain requirements, due to the fact that the hyperspace of the catalyst performance can be screened in a comparatively low amount of time. On the other hand, olefin polymerization catalysis is a tough task even for the powerful HTE technologies and, without the proper knowledge of catalysts behaviour, the reliability of these new experimental and fast techniques is never granted. The scope of the thesis is the implementation of new methods to screen the iminato catalysts in copolymerization, starting from the fundamental investigation of the catalyst behavior in copolymerization.

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