Diletto, Claudia (2014) Nanostructured polymeric materials for morphology control on nanometer scale and nanotechnology applications. [Tesi di dottorato]
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| Item Type: | Tesi di dottorato |
|---|---|
| Resource language: | English |
| Title: | Nanostructured polymeric materials for morphology control on nanometer scale and nanotechnology applications |
| Creators: | Creators Email Diletto, Claudia claudia.diletto@unina.it |
| Date: | 31 March 2014 |
| Number of Pages: | 146 |
| Institution: | Università degli Studi di Napoli Federico II |
| Department: | Scienze Chimiche |
| Scuola di dottorato: | Scienze chimiche |
| Dottorato: | Scienze chimiche |
| Ciclo di dottorato: | 26 |
| Coordinatore del Corso di dottorato: | nome email Paduano, Luigi luigi.paduano@unina.it |
| Tutor: | nome email De Rosa, Claudio UNSPECIFIED Auriemma, Finizia UNSPECIFIED |
| Date: | 31 March 2014 |
| Number of Pages: | 146 |
| Keywords: | nanomaterials; block copolymers |
| Settori scientifico-disciplinari del MIUR: | Area 03 - Scienze chimiche > CHIM/04 - Chimica industriale |
| Aree tematiche (7° programma Quadro): | NANOSCIENZE, NANOTECNOLOGIE, MATERIALE E PRODUZIONE > Nanoscienze e Nanotecnologie |
| Date Deposited: | 10 Apr 2014 08:12 |
| Last Modified: | 15 Jul 2015 01:01 |
| URI: | http://www.fedoa.unina.it/id/eprint/9942 |
Collection description
Symmetric and asymmetric poly(styrene-b-methylmethacrylate) (PS-b-PMMA) diblock copolymers (BCPs) were used as template for the incorporation of inorganic nanoparticles and/or organic molecules. Innovative nanocomposites based on a nanostructured block copolymer matrix whose lamellar and cylindrical nanodomains are selectively loaded with inorganic nanoparticles and/or organic molecules, were prepared. This study was aimed to the preparation of neat BCP and nanocomposites thin films by spin-coating and/or drop casting. Techniques as application of external electric fields and solvent annealing were developed in order to improve the morphological order of the neat copolymer and of the nanocomposites. These materials were used as substrates for surface-enhanced Raman spectroscopy (SERS) and as active layers for solar cells.
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