Cirillo, Luigi
(2010)
Synthetic Applications of Carbohydrates.
[Tesi di dottorato]
(Inedito)
| Tipologia del documento: |
Tesi di dottorato
|
| Lingua: |
English |
| Titolo: |
Synthetic Applications of Carbohydrates |
| Autori: |
| Autore | Email |
|---|
| Cirillo, Luigi | luigi.cirillo@unina.it |
|
| Data: |
30 Novembre 2010 |
| Numero di pagine: |
169 |
| Istituzione: |
Università degli Studi di Napoli Federico II |
| Dipartimento: |
Chimica organica e biochimica |
| Scuola di dottorato: |
Scienze chimiche |
| Dottorato: |
Scienze chimiche |
| Ciclo di dottorato: |
23 |
| Coordinatore del Corso di dottorato: |
| nome | email |
|---|
| Previtera, Lucio | previter@unina.it |
|
| Tutor: |
| nome | email |
|---|
| Parrilli, Michelangelo | michelangelo.parrilli@unina.it | | Bedini, Emiliano | ebedini@unina.it |
|
| Data: |
30 Novembre 2010 |
| Numero di pagine: |
169 |
| Parole chiave: |
Carbohydrates, synthesis. |
| Settori scientifico-disciplinari del MIUR: |
Area 03 - Scienze chimiche > CHIM/06 - Chimica organica |
[error in script]
[error in script]
| Depositato il: |
02 Dic 2010 08:28 |
| Ultima modifica: |
30 Apr 2014 19:45 |
| URI: |
http://www.fedoa.unina.it/id/eprint/8228 |
| DOI: |
10.6092/UNINA/FEDOA/8228 |
Abstract
In this thesis some synthetic aspects of carbohydrates will be treated. In particular, after a general introduction on the chemistry of carbohydrates,in Chapter 2 it will be explored the mechanism and synthetic potentials of the acetolysis reaction on 6-deoxysugars.
In Chapter 3 it will be proposed a new synthetic methodology for the obtainment of peptidoglycan fragments in order to have a better understanding through biological essays of how the peptidoglycan is recognized both in plants and in mammals and how possible modifications affect its biological activity.
In Chapter 4 it is proposed a new route for the synthesis of a class of glycomometics in which the two saccharide units are linked together by an urea-linkage without using the anomeric centre. The chemistry and the self-assembling properties of gluco- and galacto- urea-derivatives will be then evaluated.
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