Parisi, Emmanuele (2022) Design and structural study of novel organic and organic-inorganic hybrid compounds for advanced materials. [Tesi di dottorato]
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| Tipologia del documento: | Tesi di dottorato |
|---|---|
| Lingua: | English |
| Titolo: | Design and structural study of novel organic and organic-inorganic hybrid compounds for advanced materials |
| Autori: | Autore Email Parisi, Emmanuele emmanuele.parisi@unina.it |
| Data: | 11 Gennaio 2022 |
| Numero di pagine: | 167 |
| Istituzione: | Università degli Studi di Napoli Federico II |
| Dipartimento: | Scienze Chimiche |
| Dottorato: | Scienze chimiche |
| Ciclo di dottorato: | 34 |
| Coordinatore del Corso di dottorato: | nome email Lombardi, Angelina alombard@unina.it |
| Tutor: | nome email Centore, Roberto [non definito] Carella, Antonio [non definito] |
| Data: | 11 Gennaio 2022 |
| Numero di pagine: | 167 |
| Parole chiave: | Crystal engineering, polymorphism, organic-inorganic hybrids, advanced materials, |
| Settori scientifico-disciplinari del MIUR: | Area 03 - Scienze chimiche > CHIM/03 - Chimica generale e inorganica |
| Depositato il: | 24 Gen 2022 22:48 |
| Ultima modifica: | 28 Feb 2024 14:21 |
| URI: | http://www.fedoa.unina.it/id/eprint/14615 |
Abstract
The Crystal Engineering approach has extended its outreach into many aspects of structural science. Indeed, this tool is all about the design of molecular crystal structures and there is now greater emphasis on property design. For this reason, there is a growing effort in the development of new materials in several research fields. This Ph.D. project aims to exploit the Crystal Engineering approach to design and synthesize novel organic and organic-inorganic hybrid materials for advanced materials applications. The first part of the work deals with the application of Crystal Engineering in recent years and its use in the context of this project. In particular, chapter 2 is dedicated to polymorphism and materials for application in organic electronics. Moreover, the chalcogen bonding effect is used to drive different crystal packings for similar crystal structures. Chapter 3 describes the work carried out on novel N-rich heterocyclic compounds. In particular, I will discuss the rich tautomerism behaviour of these systems and their application in the High-Energy-Density materials research field. Lastly, Chapter 4 is focused on organic polar crystals and mechanically responsive dynamic crystals. These materials find their application as NLO active materials and optical actuators, respectively. This work was carried out in collaboration with the group of Professor Thomas Klapoetke group at the Ludwig- Maximilian University of Munich, Professor Andrea Peluso at the University of Salerno and Dr. Stefano Lettieri at CNR-ISASI.
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