Parisi, Emmanuele (2022) Design and structural study of novel organic and organic-inorganic hybrid compounds for advanced materials. [Tesi di dottorato]


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Item Type: Tesi di dottorato
Resource language: English
Title: Design and structural study of novel organic and organic-inorganic hybrid compounds for advanced materials
Date: 11 January 2022
Number of Pages: 167
Institution: Università degli Studi di Napoli Federico II
Department: Scienze Chimiche
Dottorato: Scienze chimiche
Ciclo di dottorato: 34
Coordinatore del Corso di dottorato:
Centore, RobertoUNSPECIFIED
Carella, AntonioUNSPECIFIED
Date: 11 January 2022
Number of Pages: 167
Keywords: Crystal engineering, polymorphism, organic-inorganic hybrids, advanced materials,
Settori scientifico-disciplinari del MIUR: Area 03 - Scienze chimiche > CHIM/03 - Chimica generale e inorganica
Date Deposited: 24 Jan 2022 22:48
Last Modified: 28 Feb 2024 14:21

Collection description

The Crystal Engineering approach has extended its outreach into many aspects of structural science. Indeed, this tool is all about the design of molecular crystal structures and there is now greater emphasis on property design. For this reason, there is a growing effort in the development of new materials in several research fields. This Ph.D. project aims to exploit the Crystal Engineering approach to design and synthesize novel organic and organic-inorganic hybrid materials for advanced materials applications. The first part of the work deals with the application of Crystal Engineering in recent years and its use in the context of this project. In particular, chapter 2 is dedicated to polymorphism and materials for application in organic electronics. Moreover, the chalcogen bonding effect is used to drive different crystal packings for similar crystal structures. Chapter 3 describes the work carried out on novel N-rich heterocyclic compounds. In particular, I will discuss the rich tautomerism behaviour of these systems and their application in the High-Energy-Density materials research field. Lastly, Chapter 4 is focused on organic polar crystals and mechanically responsive dynamic crystals. These materials find their application as NLO active materials and optical actuators, respectively. This work was carried out in collaboration with the group of Professor Thomas Klapoetke group at the Ludwig- Maximilian University of Munich, Professor Andrea Peluso at the University of Salerno and Dr. Stefano Lettieri at CNR-ISASI.


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