Capelli, Luigia (2010) Synthesis and reactivity of new phenolic and/or heteroaromatic systems of potential practical interest. [Tesi di dottorato] (Inedito)

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Tipologia del documento: Tesi di dottorato
Lingua: English
Titolo: Synthesis and reactivity of new phenolic and/or heteroaromatic systems of potential practical interest
Autori:
AutoreEmail
Capelli, Luigialuigia.capelli@unina.it
Data: 30 Novembre 2010
Numero di pagine: 168
Istituzione: Università degli Studi di Napoli Federico II
Dipartimento: Chimica organica e biochimica
Scuola di dottorato: Scienze chimiche
Dottorato: Scienze chimiche
Ciclo di dottorato: 23
Coordinatore del Corso di dottorato:
nomeemail
Previtera, Luciopreviter@unina.it
Tutor:
nomeemail
D'Ischia, Marcodischia@unina.it
Manini, Paolapmanini@unina.it
Data: 30 Novembre 2010
Numero di pagine: 168
Parole chiave: 5,6-dihydroxyindole;synthesis
Settori scientifico-disciplinari del MIUR: Area 03 - Scienze chimiche > CHIM/06 - Chimica organica
Depositato il: 02 Dic 2010 08:15
Ultima modifica: 30 Apr 2014 19:45
URI: http://www.fedoa.unina.it/id/eprint/8243
DOI: 10.6092/UNINA/FEDOA/8243

Abstract

My research project has been directed to the synthesis and characterization of a number of selected phenolic and/or heteroaromatic systems and their derivatives for preparation of new molecular scaffolds of potential practical interest. Most of the activity has therefore been directed to the preparation of new derivatives from 5,6-dihydroxyindole (DHI), the fundamental monomer precursors of eumelanins, and 17β-estradiol, an important human and mammal steroidal hormone, selected as biologically relevant building blocks. In particular Chapter 1 of this thesis is devoted to the synthesis of 5,6-dihydroxyindole oligomers, Chapter 2 to the synthesis and reactivity of new alkynyl-derivatives of DHI, Chapter 3 to the synthesis of new alkynyl-derivatives of 17β-estradiol. The last chapter of this thesis, Chapter 4, concerns the results of experiments started during my Master thesis and regarding the synthesis and reactivity of 9- and 10-nitrolinoleic acids, two important nitrated derivatives of linoleic acid, under physiologically relevant conditions.

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