Capelli, Luigia (2010) Synthesis and reactivity of new phenolic and/or heteroaromatic systems of potential practical interest. [Tesi di dottorato] (Unpublished)

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Item Type: Tesi di dottorato
Language: English
Title: Synthesis and reactivity of new phenolic and/or heteroaromatic systems of potential practical interest
Creators:
CreatorsEmail
Capelli, Luigialuigia.capelli@unina.it
Date: 30 November 2010
Number of Pages: 168
Institution: Università degli Studi di Napoli Federico II
Department: Chimica organica e biochimica
Doctoral School: Scienze chimiche
PHD name: Scienze chimiche
PHD cycle: 23
PHD Coordinator:
nameemail
Previtera, Luciopreviter@unina.it
Tutor:
nameemail
D'Ischia, Marcodischia@unina.it
Manini, Paolapmanini@unina.it
Date: 30 November 2010
Number of Pages: 168
Uncontrolled Keywords: 5,6-dihydroxyindole;synthesis
MIUR S.S.D.: Area 03 - Scienze chimiche > CHIM/06 - Chimica organica
Date Deposited: 02 Dec 2010 08:15
Last Modified: 30 Apr 2014 19:45
URI: http://www.fedoa.unina.it/id/eprint/8243

Abstract

My research project has been directed to the synthesis and characterization of a number of selected phenolic and/or heteroaromatic systems and their derivatives for preparation of new molecular scaffolds of potential practical interest. Most of the activity has therefore been directed to the preparation of new derivatives from 5,6-dihydroxyindole (DHI), the fundamental monomer precursors of eumelanins, and 17β-estradiol, an important human and mammal steroidal hormone, selected as biologically relevant building blocks. In particular Chapter 1 of this thesis is devoted to the synthesis of 5,6-dihydroxyindole oligomers, Chapter 2 to the synthesis and reactivity of new alkynyl-derivatives of DHI, Chapter 3 to the synthesis of new alkynyl-derivatives of 17β-estradiol. The last chapter of this thesis, Chapter 4, concerns the results of experiments started during my Master thesis and regarding the synthesis and reactivity of 9- and 10-nitrolinoleic acids, two important nitrated derivatives of linoleic acid, under physiologically relevant conditions.

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