Khan, Muhammad Rehan and fadlallah, Sami and Gallos, Antoine and Flourat, Amandine L and Torrieri, Elena and Allais, Florent (2023) Effect of ferulic acid derivative concentration on the release kinetics, antioxidant capacity, and thermal behaviour of different polymeric films. [Pubblicazione in rivista scientifica]

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Tipologia del documento: Pubblicazione in rivista scientifica
Lingua: English
Titolo: Effect of ferulic acid derivative concentration on the release kinetics, antioxidant capacity, and thermal behaviour of different polymeric films
Autori:
Autore
Email
Khan, Muhammad Rehan
Muhrehankhan.unina@outlook.com
fadlallah, Sami
[non definito]
Gallos, Antoine
[non definito]
Flourat, Amandine L
[non definito]
Torrieri, Elena
elena.torrieri@unina.it
Allais, Florent
[non definito]
Autore/i: Muhammad Rehan Khan, Sami Fadlallah, Antoine Gallos, Amandine L. Flourat, Elena Torrieri, Florent Allais
Data: 1 Giugno 2023
Istituzione: Università degli studi di Napoli Federico II
Istituzioni (extra): URD Agro-Biotechnologies Industrielles (ABI), CEBB, AgroParisTech, 3 Rue des Rouges-Terres, 51110 Pomacle, France
Dipartimento: Dipartimento di Agraria
Sezione di dipartimento: Scienze e Tecnologie Alimentari
Titolo del periodico: Food Chemistry
Data: 1 Giugno 2023
Volume: 410
Numero: 135395
Parole chiave: Release kinetics; Mathematical modelling; Ferulic acid derivative; PHAs and PLA; Antioxidant activity; Thermal behavior
Settori scientifico-disciplinari del MIUR: Area 07 - Scienze agrarie e veterinarie > AGR/15 - Scienze e tecnologie alimentari
Diritti di accesso: Accesso aperto
Depositato il: 27 Set 2023 10:17
Ultima modifica: 27 Set 2024 01:00
URI: http://www.fedoa.unina.it/id/eprint/14864
DOI: https://doi.org/10.1016/j.foodchem.2023.135395

Abstract

Ferulic acid displays poor thermal resistance during extrusion and compression moulding, slow 2,2-diphenyl-1-picrylhydrazyl (DPPH) reaction kinetics, and undetected release from polylactide (PLA) and polyhydroxyalkanoates (PHA)-based films into polar media. Thus, in this study, a ferulic acid derivative Bis-O-dihydroferuloyl-1,4-butanediol (BDF) was used as an active additive (up to 40 w%) in PLA, poly(3-hydroxybutyrate) (PHB), and poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) matrices to produce blends by extrusion. These blends were then used to prepare films by solvent casting. The BDF displayed good stability with 86–93% retention. The release kinetics in Food Simulant A revealed higher BDF release amounts (1.16–3.2%) for PHA-based films as compared to PLA. The BDF displayed faster DPPH reaction kinetics as compared to ferulic acid. The PHA-based films containing BDF displayed > 80% of DPPH inhibition. The growth of crystals inside polymer matrix had a nucleation effect which reduced the glass transition temperature of the films.

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