Cirillo, Luigi (2010) Synthetic Applications of Carbohydrates. [Tesi di dottorato] (Inedito)
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| Tipologia del documento: | Tesi di dottorato |
|---|---|
| Lingua: | English |
| Titolo: | Synthetic Applications of Carbohydrates |
| Autori: | Autore Email Cirillo, Luigi luigi.cirillo@unina.it |
| Data: | 30 Novembre 2010 |
| Numero di pagine: | 169 |
| Istituzione: | Università degli Studi di Napoli Federico II |
| Dipartimento: | Chimica organica e biochimica |
| Scuola di dottorato: | Scienze chimiche |
| Dottorato: | Scienze chimiche |
| Ciclo di dottorato: | 23 |
| Coordinatore del Corso di dottorato: | nome email Previtera, Lucio previter@unina.it |
| Tutor: | nome email Parrilli, Michelangelo michelangelo.parrilli@unina.it Bedini, Emiliano ebedini@unina.it |
| Data: | 30 Novembre 2010 |
| Numero di pagine: | 169 |
| Parole chiave: | Carbohydrates, synthesis. |
| Settori scientifico-disciplinari del MIUR: | Area 03 - Scienze chimiche > CHIM/06 - Chimica organica |
| Depositato il: | 02 Dic 2010 08:28 |
| Ultima modifica: | 30 Apr 2014 19:45 |
| URI: | http://www.fedoa.unina.it/id/eprint/8228 |
| DOI: | 10.6092/UNINA/FEDOA/8228 |
Abstract
In this thesis some synthetic aspects of carbohydrates will be treated. In particular, after a general introduction on the chemistry of carbohydrates,in Chapter 2 it will be explored the mechanism and synthetic potentials of the acetolysis reaction on 6-deoxysugars. In Chapter 3 it will be proposed a new synthetic methodology for the obtainment of peptidoglycan fragments in order to have a better understanding through biological essays of how the peptidoglycan is recognized both in plants and in mammals and how possible modifications affect its biological activity. In Chapter 4 it is proposed a new route for the synthesis of a class of glycomometics in which the two saccharide units are linked together by an urea-linkage without using the anomeric centre. The chemistry and the self-assembling properties of gluco- and galacto- urea-derivatives will be then evaluated.
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