Cirillo, Luigi (2010) Synthetic Applications of Carbohydrates. [Tesi di dottorato] (Unpublished)

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Item Type: Tesi di dottorato
Language: English
Title: Synthetic Applications of Carbohydrates
Creators:
CreatorsEmail
Cirillo, Luigiluigi.cirillo@unina.it
Date: 30 November 2010
Number of Pages: 169
Institution: Università degli Studi di Napoli Federico II
Department: Chimica organica e biochimica
Doctoral School: Scienze chimiche
PHD name: Scienze chimiche
PHD cycle: 23
PHD Coordinator:
nameemail
Previtera, Luciopreviter@unina.it
Tutor:
nameemail
Parrilli, Michelangelomichelangelo.parrilli@unina.it
Bedini, Emilianoebedini@unina.it
Date: 30 November 2010
Number of Pages: 169
Uncontrolled Keywords: Carbohydrates, synthesis.
MIUR S.S.D.: Area 03 - Scienze chimiche > CHIM/06 - Chimica organica
Date Deposited: 02 Dec 2010 08:28
Last Modified: 30 Apr 2014 19:45
URI: http://www.fedoa.unina.it/id/eprint/8228

Abstract

In this thesis some synthetic aspects of carbohydrates will be treated. In particular, after a general introduction on the chemistry of carbohydrates,in Chapter 2 it will be explored the mechanism and synthetic potentials of the acetolysis reaction on 6-deoxysugars. In Chapter 3 it will be proposed a new synthetic methodology for the obtainment of peptidoglycan fragments in order to have a better understanding through biological essays of how the peptidoglycan is recognized both in plants and in mammals and how possible modifications affect its biological activity. In Chapter 4 it is proposed a new route for the synthesis of a class of glycomometics in which the two saccharide units are linked together by an urea-linkage without using the anomeric centre. The chemistry and the self-assembling properties of gluco- and galacto- urea-derivatives will be then evaluated.

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