Cirillo, Luigi (2010) Synthetic Applications of Carbohydrates. [Tesi di dottorato] (Inedito)

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Tipologia del documento: Tesi di dottorato
Lingua: English
Titolo: Synthetic Applications of Carbohydrates
Autori:
AutoreEmail
Cirillo, Luigiluigi.cirillo@unina.it
Data: 30 Novembre 2010
Numero di pagine: 169
Istituzione: Università degli Studi di Napoli Federico II
Dipartimento: Chimica organica e biochimica
Scuola di dottorato: Scienze chimiche
Dottorato: Scienze chimiche
Ciclo di dottorato: 23
Coordinatore del Corso di dottorato:
nomeemail
Previtera, Luciopreviter@unina.it
Tutor:
nomeemail
Parrilli, Michelangelomichelangelo.parrilli@unina.it
Bedini, Emilianoebedini@unina.it
Data: 30 Novembre 2010
Numero di pagine: 169
Parole chiave: Carbohydrates, synthesis.
Settori scientifico-disciplinari del MIUR: Area 03 - Scienze chimiche > CHIM/06 - Chimica organica
Depositato il: 02 Dic 2010 08:28
Ultima modifica: 30 Apr 2014 19:45
URI: http://www.fedoa.unina.it/id/eprint/8228
DOI: 10.6092/UNINA/FEDOA/8228

Abstract

In this thesis some synthetic aspects of carbohydrates will be treated. In particular, after a general introduction on the chemistry of carbohydrates,in Chapter 2 it will be explored the mechanism and synthetic potentials of the acetolysis reaction on 6-deoxysugars. In Chapter 3 it will be proposed a new synthetic methodology for the obtainment of peptidoglycan fragments in order to have a better understanding through biological essays of how the peptidoglycan is recognized both in plants and in mammals and how possible modifications affect its biological activity. In Chapter 4 it is proposed a new route for the synthesis of a class of glycomometics in which the two saccharide units are linked together by an urea-linkage without using the anomeric centre. The chemistry and the self-assembling properties of gluco- and galacto- urea-derivatives will be then evaluated.

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